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WORKING WITH OXIDIZERS


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Posted

All should be aware that some oxidizers "give up" their O2 more easily than others, some VERY easily. For that reason, IMO it is good policy to study this fact in advance of crushing stuff in a mixing device haphazardly.

 

Potassium chlorate is a good example of rather treacherous oxidizer. For that reason, potassium Perchlorate has supplanted it often. Chlorate mixtures have been known to ignite or explode due to inertial setback in shells fired from mortar tubes. If that happens, an emergency on the ground is likely.

 

Oxygen is contained in a great variety of chemical compounds: nitrates, carbonates, chlorates, oxalates, permanganates, peroxides, hypochlorite, and the like, and these are usually contained in compound form such as magnesium nitrate, potassium permanganate, sodium chlorate, etc.

 

They do not all react at similar rates; some react little or not at all. Thus strontium carbonate, for example, may be used to impart red color, but provides little "oomph" to the reaction: other oxidizer s needed.

 

"Throwing things together" in this game is a serious mistake.

Posted

"Chlorate mixtures have been known to ignite or explode due to inertial setback in shells fired from mortar tubes."

 

And how was this determined?

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Posted

"Chlorate mixtures have been known to ignite or explode due to inertial setback in shells fired from mortar tubes."

 

And how was this determined?

 

Well, depending on how questioning you happen to be, I could say I pulled the determination out of my ass. But, setback has always been a serious consideration for the big guys, military, so thus it does happen for whatever reason.

 

I might suggest you consult with the work by Tenney L. Davis.

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